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Table 4 Precision, repeatability of seven analytes

From: Chemical fingerprinting and quantitative constituent analysis of Siwu decoction categorized formulae by UPLC-QTOF/MS/MS and HPLC-DAD

Analytes

Precision (RSD,%)

Repeatability (RSD,%; n = 6)

Intraday (n = 6)

Interday (n = 6)

SWD

SFZYD

XFSWD

THSWD

QLSWD

Gallic acid

1.75

1.78

1.81

1.26

2.84

3.32

1.31

Protocatechuic acid

0.76

1.21

3.16

1.90

2.72

4.18

3.19

Vanillic acid

1.31

1.55

1.79

1.05

2.26

3.97

2.80

Caffeic acid

0.98

0.97

2.27

2.47

1.60

4.52

3.04

Paeoniflorin

1.06

2.01

2.72

3.58

2.38

3.96

2.19

Ferulic acid

0.88

1.05

2.19

3.01

1.26

2.95

2.22

Senkyunolide I

1.16

1.12

2.22

3.97

1.43

1.82

3.75