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Table 1 Chemical constituents identified from CF

From: Corni Fructus: a review of chemical constituents and pharmacological activities

No.

Chemical class

Compound name

Chemical formula

Exact mass

References

 

Terpenoids

1

Iridoids

Sweroside

C16H22O9

358.1264

[73]

2

Loganic acid

C16H24O10

376.1369

[19]

3

Cornin

C17H24O10

388.1369

[73]

4

7-Dehydrologanin

C17H24O10

388.1369

[74]

5

Loganin

C17H26O10

390.1526

[74]

6

7-α-Morroniside

C17H26O11

406.1475

[75]

7

7-β-Morroniside

C17H26O11

406.1475

[75]

8

7-α-O-Methyl-morroniside

C18H28O11

420.1632

[75]

9

7-β-O-Methyl-morroniside

C18H28O11

420.1632

[75]

10

7-α-O-Ethyl-morroniside

C18H29O11

421.1710

[75]

11

7-β-O-Ethyl-morroniside

C18H29O11

421.1710

[75]

12

7-α-O-Butyl-morroniside

C21H34O11

462.2101

[43]

13

7-β-O-Dimethyl-butanedioate morroniside

C23H34O15

550.1898

[76]

14

Logmalicids A

C21H29O14

505.1557

[24]

15

Logmalicids B

C21H29O14

505.1557

[24]

16

Cornusfuroside A

C25H34O13

542.1999

[77]

17

Cornusfuroside B

C25H34O13

542.1999

[77]

18

Cornusfuroside C

C25H34O13

542.1999

[77]

19

Cornusfuroside D

C29H34O15

622.1898

[77]

20

Secoiridoids

Linalool

C10H18O

154.1358

[78]

21

Linalool oxide

C10H18O2

170.1307

[79]

22

Secoxyloganin

C17H24O11

404.1319

[24]

23

Cornuside

C24H30O14

542.1636

[74]

24

Triterpenoids

Ursolic acid

C30H48O3

456.3603

[74]

25

Oleanolic acid

C30H48O3

456.3603

[15]

26

Arjunglucoside II

C36H58O10

650.4030

[74]

 

Flavonoids

27

 

Naringenin

C15H12O5

272.0685

[74]

28

Kaempferol

C15H10O6

286.0477

[79]

29

Kaempferide

C16H12O6

300.0634

[80]

30

Kaempferol-3-O-β-d-galactopyranoside

C21H20O11

448.1006

[24]

31

Kaempferol-3-O-β-d-glucoside

C21H20O11

448.1006

[74]

32

Kaempferol-3-O-β-d-rutinoside

C27H30O15

594.1585

[24]

33

Quercetin

C15H10O7

302.0427

[79]

34

Quercetin-3-O-β-d-galactopyranoside

C21H20O12

464.0955

[24]

35

Quercetin-3-O-β-d-glucuronide

C21H18O13

478.0747

[24]

36

Quercetin-3-O-β-d-glucuronide methyl ester

C22H20O13

492.0904

[24]

37

Quercetin-3-O-β-d-(6-n-butyl glucuronide)

C25H25O13

533.1295

[15]

38

(−)-Epicatechin-3-O-gallate

C22H18O10

442.0900

[15]

39

Isoquercitrin

C21H20O12

464.0955

[80]

 

Tannins

40

 

Gallic acid

C7H6O5

170.0215

[74]

41

7-O-Galloyl-d-sedoheptulose

C14H18O11

362.0849

[19]

42

Gemin D

C27H22O18

634.0806

[6, 7]

43

Oenothein C

C34H24O22

784.0759

[6, 7]

44

3-O-Galloyl-d-glucose

C13H16O10

332.0743

[6, 7]

45

2,3-Di-O-galloyl-d-glucose

C20H20O14

484.0853

[6, 7]

46

1,2,3-Tri-O-galloyl-β-d-glucose

C27H24O18

636.0963

[6, 7]

47

1,2,6-Tri-O-galloyl-β-d-glucose

C27H24O18

636.0963

[6, 7]

48

1,2,3,6-Tetra-O-galloyl-β-d-glucose

C34H28O22

788.1072

[6, 7]

49

Tellimagrandin I

C34H26O22

786.0916

[6, 7]

50

Tellimagrandin II

C41H30O26

938.1025

[6, 7]

51

Isocoriariin F

C34H26O23

802.0865

[6, 7]

52

Coriariin F

C34H26O23

802.0865

[6, 7]

53

Rugosin B

C41H30O27

954.0974

[6, 7]

54

Isorugosin B

C41H30O27

954.0974

[6, 7]

55

Isoterchebin

C41H30O27

954.0974

[6, 7]

56

Isorugosin A

C48H34O31

1106.1084

[6, 7]

57

Rugosin D

C82H58O52

1874.1894

[6, 7]

58

Isorugosin D

C82H58O52

1874.1894

[6, 7]

59

Camptothin A

C61H46O40

1418.1565

[6, 7]

60

Camptothin B

C75H54O48

1722.1785

[6, 7]

61

Cornusiin B

C48H30O30

1086.0822

[6, 7]

62

Cornusiin A

C68H50O44

1570.1675

[6, 7]

63

Cornusiin D

C75H54O48

1722.1785

[6, 7]

64

Cornusiin E

C82H58O52

1874.1894

[6, 7]

65

Cornusiin F

C95H70O62

2202.2325

[6, 7]

66

Cornusiin C

C102H74O66

2354.2434

[6, 7]

67

Methyl tri-O-methylgallate

C11H14O5

226.0841

[6, 7]

68

Dimethyl hexamethoxydiphenate

C22H26O10

450.1526

[6, 7]

69

Trimethyl-octa-O-methylvaloneate

C32H36O15

660.2054

[6, 7]

 

Polysaccharides

70

 

Co-4

  

[8]

71

COP-1

  

[9]

72

COP-2

  

[9]

73

COP-3

  

[9]

74

COP-4

  

[9]

75

FCAP1

  

[81]

76

FCP5-A

  

[8]

77

PFCA-III

  

[8]

78

PFCC-I

  

[8]

79

SZYP-2

  

[8]

 

Other compounds

80

Phenylpropanoids

p-Hydroxycinnamic acid

C9H8O3

164.0473

[74]

81

Caffeic acid

C9H8O4

180.0423

[15]

82

Caftaric acid monomethyl ester

C14H14O9

326.2556

[15]

83

Caffeoyltartaric acid dimethyl ester

C15H16O9

340.0794

[76]

84

Sterols

β-Sitosterol

C29H50O

414.7067

[15]

85

Daucosterol-6′-malate

C39H64O10

692.4499

[80]

86

Carboxylic acids

Succinic acid

C4H6O4

118.0266

[85]

87

Malic acid

C4H6O5

134.0215

[85]

88

Methylmalic acid

C5H8O5

148.0372

[74]

89

Citric acid

C6H8O7

192.0270

[85]

90

Butoxysuccinic acid

C8H14O5

190.1938

[15]

91

Furans

5-Hydroxymethylfurfural

C6H6O3

126.0317

[73]

92

Dimethyltetrahydrofuran cis-2,5-dicarboxylate

C8H12O5

188.0685

[79]

93

Mineral substances

Ca, Fe, K, Mg, Mn, Zn

  

[82]