Sample | Detection method | Analytical method | References |
---|---|---|---|
Lonicerae japonicae Flos | NIRS | Multivariate statistical process control (MSPC) model, PCA | [67] |
Cefazolin sodium pentahydrate Cephathiamidine | NIRS | One-way analysis, factor analysis, cluster analysis | [68] |
Ramulus cinnamomi | Microscale thermophoresis On-line NIR-HPLC | Sipls, PLS model | [69] |
Acetylsalicylic acid tablets | NIR-CI | Multivariate curve resolution-alternating least squares | [73] |
Yinhuang dispersible tablets | NIR-CI | Basic analysis of correlation between analytes | [74] |
Coptis | NIR diffuse reflectance spectroscopy | MSC, PLS, ANN | [75] |
Rukuaixiao tablets | N/MIR diffuse reflectance spectral imaging | Correlation analysis method | [108] |
Compound Liquorice tablets | NIR-CI | Basic analysis of correlation between analytes, PCA | [109] |
Flos Lonicera japonica | NIR-CI | Basic analysis of correlation between analytes, moving block macropixel relative standard deviation | [110] |
Shenzhiling oral Liquid | NIRS | PLSR, support vector machine regression (SVMR) | [111] |
Wangbi tablets | NIRS | CARS-PLSR model | [112] |
Flos Lonicerae Japonicae | NIRS | Synergy interval PLS (Si-GA-PLS) | [113] |
Acetaminophen, SiO2, MCC, HPMC | Low-resolution Raman spectra | PCA, PLS | [79] |
Entecavir tablets | Raman spectra, X-ray powder diffraction, differential scanning calorimetric | Thermo-gravimetric analysis (TGA) | [80] |
Atropine sulfate | LC–MS/MS, Raman-CI, X-ray powder diffraction | SA | [82] |
Cinnabar | Surface-enhanced Raman spectrum | Curve fitting | [83] |
Artemisia annua L. | Laser Raman spectroscopy | Curve fitting | [114] |
Cornu Caprae Hircus | Raman spectra, | PLS, HCA | [115] |
Brufen, Glucosamine, Glucosamine, Paracetamol | LIBS | PCA, SIMCA | [86] |
Blumea balsamifera DC | LIBS | PCA, PLS-DA model | [87] |
Renqing Mangjue, Renqing Changjue, 25-herb coral Pills, 25-herb pearl Pills | LIBS | National Institute of Standard and Technology (NIST) | [88] |
Juncus effusus L. | LIBS | Elemental microanalysis | [89] |
An-Gong-Niu-Huang Wan | LIBS | RCCR, MWSD | |
Ligusticum wallichii | LIBS | Multiple linear regression models | [92] |
Angelica pubescens Codonopsis pilosula Ligusticum wallichii | LIBS | PCA, ANN, LDA | [93] |
Sustained-release felodipine tablets | SR-μCT | Data visualization | [98] |
Captopril osmotic pump tablets | SR-μCT | Data visualization | [99] |
Advicor | First and third derivative UV spectrophotometry | H-point standard addition method | [102] |
Qingkailing injection | UV spectra | LS-SVM | [103] |
Propolis | NIRS, HPTLC, FLD | PLS-R, HCA, OPLS-DA | [107] |
San-Huang tablets | Spectral quantitative fingerprinting (UV, FT-IR, CH) | SQFM | [116] |