No | Stability RSD (%) (n = 6) | Repeatability RSD (%) (n = 6) | Precision | Recovery (n = 6) | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Intra-day RSD (%) (n = 6) | Inter-day RSD (%) (n = 3) | Sample (g) | Original (µg) | Spiked (µg) | Found (µg) | Recovery (%) | Average recovery (%) | RSD (%) | |||
1 | 3.41 | 3.12 | 2.73 | 2.85 | 0.502 | 1.009 | 1.092 | 2.383 | 125.87 | Â | Â |
0.502 | 1.009 | 1.092 | 2.654 | 150.67 | Â | Â | |||||
0.503 | 1.011 | 1.092 | 2.418 | 128.81 | 134.46 | 7.91 | |||||
0.512 | 1.029 | 1.092 | 2.583 | 142.33 | Â | Â | |||||
0.501 | 1.007 | 1.092 | 2.494 | 136.14 | Â | Â | |||||
0.518 | 1.041 | 1.092 | 2.383 | 122.92 | Â | Â | |||||
2 | 3.55 | 3.24 | 1.68 | 2.79 | 0.502 | 0.512 | 0.535 | 1.184 | 125.61 | Â | Â |
0.502 | 0.512 | 0.535 | 1.318 | 150.65 | Â | Â | |||||
0.503 | 0.513 | 0.535 | 1.203 | 128.97 | Â | Â | |||||
0.512 | 0.522 | 0.535 | 1.328 | 150.65 | 134.05 | 9.70 | |||||
0.501 | 0.511 | 0.535 | 1.183 | 125.61 | Â | Â | |||||
0.518 | 0.528 | 0.535 | 1.185 | 122.80 | Â | Â | |||||
3 | 3.64 | 1.92 | 2.58 | 2.12 | 0.502 | 0.512 | 0.594 | 1.345 | 140.29 | Â | Â |
0.502 | 0.512 | 0.594 | 1.430 | 154.48 | Â | Â | |||||
0.503 | 0.513 | 0.594 | 1.390 | 147.60 | Â | Â | |||||
0.512 | 0.522 | 0.594 | 1.454 | 156.79 | 150.04 | 3.88 | |||||
0.501 | 0.511 | 0.594 | 1.398 | 149.35 | Â | Â | |||||
0.518 | 0.528 | 0.594 | 1.430 | 151.73 | Â | Â | |||||
4 | 3.47 | 1.23 | 2.22 | 4.05 | 0.502 | 0.638 | 0.672 | 1.505 | 129.15 | Â | Â |
0.502 | 0.638 | 0.672 | 1.674 | 154.28 | Â | Â | |||||
0.503 | 0.639 | 0.672 | 1.492 | 126.94 | 143.88 | 8.68 | |||||
0.512 | 0.650 | 0.672 | 1.683 | 153.70 | Â | Â | |||||
0.501 | 0.636 | 0.672 | 1.630 | 147.93 | Â | Â | |||||
0.518 | 0.658 | 0.672 | 1.674 | 151.26 | Â | Â | |||||
5 | 3.95 | 1.97 | 2.11 | 4.63 | 0.502 | 2.113 | 2.131 | 4.159 | 96.01 | Â | Â |
0.502 | 2.113 | 2.131 | 4.457 | 109.99 | Â | Â | |||||
0.503 | 2.118 | 2.131 | 4.230 | 99.11 | Â | Â | |||||
0.512 | 2.156 | 2.131 | 4.430 | 106.71 | 105.53 | 9.65 | |||||
0.501 | 2.109 | 2.131 | 4.201 | 98.17 | Â | Â | |||||
0.518 | 2.181 | 2.131 | 4.806 | 123.18 | Â | Â | |||||
6 | 3.73 | 3.30 | 1.67 | 2.90 | 0.502 | 1.531 | 1.512 | 3.051 | 100.52 | Â | Â |
0.502 | 1.531 | 1.512 | 3.092 | 103.20 | Â | Â | |||||
0.503 | 1.534 | 1.512 | 3.106 | 103.98 | Â | Â | |||||
0.512 | 1.562 | 1.512 | 3.289 | 114.24 | 104.38 | 6.19 | |||||
0.501 | 1.528 | 1.512 | 2.974 | 95.66 | Â | Â | |||||
0.518 | 1.580 | 1.512 | 3.224 | 108.71 | Â | Â |