Table 1 Active ingredients of GQWTF
No | Peak No.a | RT (min) | M+H | Product ion | Identification result | Chemical structure |
|---|---|---|---|---|---|---|
1 | 2 | 4.804 | 354.2853 | 321.1312;305.1577;300.2020;283.1756 | N-Methylcanadine |
|
2 | 5 | 6.632 | 453.2111 | 437.2361;432.2805;415.2533 | Cyclo tetraleucyl |
|
3 | 6 | 7.134 | 903.4887; 957.5079 | 925.4880;741.4484 | Timosaponin C |
|
4 | 7 | 7.173 | 497.2362 | 481.2635;476.3075 | Oxypaeoniflorin |
|
5 | 10 | 8.125 | 585.2885 | 569.3146;564.3591;547.3326 | Benzoylpaeoniflorin |
|
6 | 17 | 11.522 | 969.5364 | 789.4799;461.3982;443.3825 | Ginsenoside Rd |
|
7 | 18 | 13.864 | 1109.6099 | 1131.5977 | Ginsenoside Rb1 |
|
8 | 19 | 14.044 | 1101.5818 | 947.5421; 785.4781; 461.3992 | Ginsenoside Rc |
|
9 | 20 | 16.13 | 343.2959 | 365.2782; 250.1779;240.2325 | 1-O-caffeoyl glucoside |
|
10 | 21 | 16.54 | 314.1746 | 286.1446; 272.1521 | Armepavine |
|
11 | 25 | 18.39 | 355.1047 | 259.1665;237.1842;124.0868 | Chlorogenic acid |
|
12 | 26 | 19.707 | 463.2819 | 259.1099;243.1355 | Lactiflorin |
|
13 | 30 | 21.097 | 579.2934 | 383.2043;301.1412 | Timosaponin AI |
|
14 | 32 | 22.408 | 827.4404 | 684.2042;425.2144;301.1410 | Esculentoside A |
|
15 | 33 | 23.258 | 331.2245 | 309.2423; 301.13 | Iristectorigenin |
|
16 | 35 | 23.953 | 637.306 | 659.2884 | Ginsenoside Rh4 |
|
