Table 2 Evaluation of Compounds obtained from CD and its processed products by UPLC-Q-TOF-MS^E

1

Kankanoside B

C₁₅H₂₄O₁₀

 + HCOO

0.2

363.12870, 183.06693, 153.05619

CD, CD-HP

2

6-Deoxycatalpol

C₁₅H₂₂O₉

 + HCOO

0.5

391.12447, 341.10886,

CD, CD-NP, CD-HP

3

6-Deoxycatalpol

C₁₅H₂₂O₉

 + HCOO

0.5

391.12448, 183.06662

CD, CD-HP

4

Androsin

C₁₅H₂₀O₈

 + HCOO

0.8

373.11434, 211.06188, 193.05142

CD, CD-NP, CD-HP

5

6-Deoxycatalpol

C₁₅H₂₂O₉

 + HCOO

0.5

391.12446, 229.07232, 167.03571

CD, CD-NP, CD-HP

6

Androsin

C₁₅H₂₀O₈

 + HCOO

1.2

373.11471, 299.11294, 211.06206, 149.06137

CD, CD-NP, CD-HP

7

Kankanoside L

C₁₅H₂₄O₉

 + HCOO

0.7

393.14046, 315.10749, 206.06863, 134.04736

CD, CD-NP, CD-HP

8

kankanoside M

C₁₅H₂₂O₈

 + HCOO

0.6

375.12966, 213.07775, 125.06127

CD, CD-NP, CD-HP

9

3,4-dimethoxybenzyl-β-d-glucoside

C₁₆H₂₄O₁₀

–H

0.8

375.12994, 255.08683, 213.07767, 151.07707

CD, CD-NP, CD-HP

10

Decaffeoylacteoside

C₂₀H₃₀O₁₂

–H

0

461.16591, 315.10891, 135.04591

CD, CD-NP, CD-HP

11

Kankanoside F

C₂₆H₄₀O₁₇

–H

0.5

623.21920, 461.16678, 315.10994, 135.04591

CD, CD-NP, CD-HP

12

Gluroside

C₁₅H₂₄O₈

 + HCOO

0.1

377.14491, 461.16609, 315.10891, 135.04591

CD, CD-NP, CD-HP

13

Cistantubulose A1

C₂₇H₃₈O₁₈

–H

0.7

649.19871, 537.18251, 335.09146, 179.03598,

CD, CD-NP, CD-HP

14

6-deoxycatalpol

C₁₅H₂₂O₉

–H

0.7

345.11929, 299.11424, 179.03598

CD, CD-NP, CD-HP

15

Adoxosidic acid

C₁₆H₂₄O₁₀

–H

− 1.1

213.07683

CD, CD-NP, CD-HP

16

Cistanoside F

C₂₁H₂₈O₁₃

–H

− 0.1

487.14512, 325.09503, 251.05822, 179.03637

CD, CD-NP, CD-HP

17

Sinapic aldehyde 4-O-β-d-glucopyranoside

C₁₆H₂₀O₉

 + HCOO

0.3

401.10872, 301.09,397, 283.08371, 193.05148

CD, CD-NP, CD-HP

18

Kankanose

C₂₇H₃₈O₁₈

–H

0.5

649.19853, 461.16139, 293.12495, 179.03612

CD, CD-NP, CD-HP

19

3-Methyl-but-2-en-1-yl-β-d-glucopyranoside

C₁₁H₂₀O₆

 + HCOO

1.3

293.12494, 195.06673, 179.03612

CD, CD-NP, CD-HP

20

Demethylsyringing

C₁₆H₂₂O₉

–H

0.7

357.11931, 251.05778, 195.06,678, 179.03653

CD, CD-NP, CD-HP

21

Cistanoside G

C₂₀H₃₀O₁₁

–H

− 0.1

445.17092, 375.13013, 293.12548, 195.06823, 179.03678

CD, CD-NP, CD-HP

22

Cistanoside F

C₂₁H₂₈O₁₃

–H

− 0.6

487.14577, 445.17102,323.08273, 179.03678,

CD, CD-NP, CD-HP

23

3-Methyl-but-2-en-1-yl-β-D-glucopyranoside

C₁₁H₂₀O₆

 + HCOO

1.5

293.12505, 161.04759

CD, CD-NP, CD-HP

24

Gluroside

C₁₅H₂₄O₈

 + HCOO

0.7

377.14547, 293.12505, 179.03614

CD, CD-HP

25

Cistanoside F

C₂₁H₂₈O₁₃

–H

0.5

487.14668, 2,23.06196, 179.03779

CD, CD-NP, CD-HP

26

Kankanoside D

C₁₅H₂₆O₇

 + HCOO

0.8

363.16634, 315.10883, 179.03855, 161.04465

CD, CD-NP, CD-HP

27

Cistanoside E

C₂₁H₃₂O₁₂

–H

5.3

475.18694, 363.16559, 179.03,855

CD, CD-NP, CD-HP

28

Cistanoside I

C₂₁H₂₈O₁₂

–H

0.2

471.15048, 369.11987, 471.15071, 179.03589, 163.04110

CD, CD-NP, CD-HP

29

Cistanoside F

C₂₁H₂₈O₁₃

–H

1.4

487.14656, 323.07922, 251.05793, 179.03699

CD, CD-NP, CD-HP

30

Cistanoside F

C₂₁H₂₈O₁₃

–H

1.2

487.14637, 323.08028, 251.05805, 179.03769

CD, CD-NP, CD-HP

31

Androsin

C₁₅H₂₀O₈

–H

1.2

327.10918, 251.05805, 179.03769, 131.07201

CD, CD-NP, CD-HP

32

Cistanoside H

C₂₂H₃₂O₁₃

–H

− 0.4

503.17610, 461.16590, 375.13036, 315.10972, 135.04603

CD, CD-NP, CD-HP

33

Kankanoside E

C₁₆H₂₈O₈

 + HCOO

− 0.1

393.17603, 241.11923, 375.13036, 161.03814

CD, CD-HP

34

Cistantubuloside C 1 /C 2

C₃₅H₄₆O₂₁

–H

3.4

801.24867, 623.20258, 110.03824

CD, CD-NP, CD-HP

35

(2E,6Z)-2-β-d-Glucopyranosyloxy-2,6-dimethyl-2,6-octadienoic acid

C₁₆H₂₆O₈

 + HCOO

0.4

391.16080, 345.15509, 163.03730

CD, CD-NP, CD-HP

36

Kankanoside E

C₁₆H₂₈O₈

 + HCOO

0.5

393.17656, 283.07834, 179.03768

CD, CD-NP, CD-HP

37

Campneoside II

C₂₉H₃₆O₁₆

–H

0.1

621.19264, 361.15007, 161.02704

CD, CD-NP, CD-HP

38

Echinacoside

C₃₅H₄₆O₂₀

–H

4.5

785.25485, 623.21903, 392.11650, 179.03596

CD, CD-NP, CD-HP

39

8-hydroxygeraniol-1-β-d-glucopyranoside

C₁₆H₂₈O₇

 + HCOO

0.1

377.18129, 331.14023, 164.07382

CD, CD-NP, CD-HP

40

Cistanoside E

C₂₁H₃₂O₁₂

–H

− 0.3

347.17188, 251.05915

CD, CD-NP, CD-HP

41

Liriodendrin

C₃₄H₄₆O₁₈

 + HCOO

0.9

787.26703, 579.20978, 475.18047, 417.15414

CD, CD-NP

42

Isolariciresinol-9′-O-β-d-glucopyranoside

C₂₆H₃₄O₁₁

 + HCOO

− 0.2

567.20755, 359.14970, 329.13966, 178.06231

CD, CD-NP, CD-HP

43

Campneoside II

C₂₉H₃₆O₁₆

–H

1.1

639.19362, 487.14472, 251.05630

CD, CD-NP, CD-HP

44

Kankanosides K 1 /K 2

C₃₆H₄₈O₂₁

–H

2.6

815.26358, 783.23518, 637.1979, 381.15558, 179.03631

CD, CD-NP, CD-HP

45

Cistantubuloside B 1

C₃₅H₄₆O₁₉

–H

1.8

769.25732, 623.21303, 420.06489, 163.03926

CD, CD-NP, CD-HP

46

8-hydroxygeraniol-1-β-d-glucopyranoside

C₁₆H₂₈O₇

 + HCOO

0.8

377.18204, 367.15243, 163.04196

CD, CD-NP, CD-HP

47

Kankanoside N

C₁₆H₂₆O₈

–H

1.4

345.15630, 197.80891, 113.02490

CD, CD-NP, CD-HP

48

Cistanoside A

C₃₆H₄₈O₂₀

 + HCOO

5.4

845.27689, 799.27001,681.20502

CD, CD-NP, CD-HP

49

Kankanoside I

C₃₅H₄₆O₁₈

 + HCOO

4.2

799.27031, 365.08428, 161.02522

CD, CD-NP, CD-HP

50

(2E,6E)-2-β-d-glucopyranosyloxy-2,6-dimethyl-2,6-octadienoic acid

C₁₆H₂₆O₈

–H

1.6

345.15649, 165.09327

CD, CD-NP, CD-HP

51

Kankanoside A

C₁₆H₂₆O₈

–H

1.6

345.15647, 195.06666, 179.03628

CD, CD-NP, CD-HP

52

Cistanoside C

C₃₀H₃₈O₁₅

 + HCOO

1.1

683.21978, 489.14915, 417.15349, 335.20636, 197.80796

CD, CD-NP, CD-HP

53

kankanoside E

C₁₆H₂₈O₈

–H

1.0

347.17157, 195.81307, 167.10929

CD, CD-NP, CD-HP

54

Acteoside

C₂₉H₃₄O₁₅

–H

1.6

623.19917, 461.16657, 315.10988, 161.02530

CD, CD-NP, CD-HP

55

Tubuloside A

C₃₇H₄₈O₂₁

–H

4.5

827.26548, 621.18343, 469.13652, 379.19635

CD, CD-NP, CD-HP

56

Cistanoside B

C₃₇H₅₀O₂₀

 + HCOO

4.1

859.2913, 679.18910, 565.19246

CD, CD-NP, CD-HP

57

Cistanoside J

C₃₃H₄₂O₁₆

 + HCOO

4.0

739.24093, 345.15468, 161.02597

CD, CD-NP, CD-HP

58

Tubuloside A

C₃₇H₄₈O₂₁

–H

3.9

827.26486, 739.24745, 579.22756, 345.15468, 161.02597

CD-NP, CD-HP

59

Kankanoside E

C₁₆H₂₈O₈

–H

1.3

347.17191, 303.18323, 211.13616, 185.11917,

CD, CD-NP, CD-HP

60

Acteoside

C₂₉H₃₆O₁₅

–H

1.9

623.19954, 461.16624, 161.02546

CD, CD-NP, CD-HP

61

Crenatoside

C₂₉H₃₄O₁₅

–H

1.4

621.18331, 387.14418, 179.03640

CD, CD-NP, CD-HP

62

Kankanosides K1/K2

C₃₆H₄₈O₂₁

–H

2.1

499.1811, 197.8080, 160.8423

CD-HP

63

Kankanoside H1

C₃₇H₄₈O₂₀

–H

− 0.8

607.20431, 445.17033, 161.02556

CD, CD-HP

64

Isosyringalide-3´-α-L-rhamnopyranoside

C₂₉H₃₆O₁₄

–H

0.7

607.20341, 461.16447, 315.10906, 145.03063

CD, CD-NP, CD-HP

65

Campneoside I

C₃₀H₃₈O₁₆

–H

1.6

607.20440, 461.16367, 443.15204, 145.03081

CD, CD-NP, CD-HP

66

Cis-isocistanoside C

C₃₀H₃₈O₁₅

–H

1.5

637.21474, 475.18074, 329.12012, 161.02576

CD, CD-NP, CD-HP

67

Citrusin A

C₂₇H₃₆O₁₁

 + HCOO

0.1

581.22351, 433.15241,371.13360,343.1457

CD, CD-NP, CD-HP

68

Isosyringalise-3´-ɑ-L-rhamnopyranoside

C₂₉H₃₆O₁₄

–H

0.6

607.20334, 461.15822, 161.02611

CD, CD-NP, CD-HP

69

Isocampneoside I

C₃₀H₃₈O₁₆

–H

1.2

607.2094, 461.16616, 307.08417, 145.03058

CD, CD-NP, CD-HP

70

Syringalide A-3´-α-L-rhamnopyranoside

C₂₉H₃₆O₁₄

–H

1.0

607.20372, 461.16616, 307.08417, 145.03089

CD, CD-NP, CD-HP

71

isocistanoside C

C₃₀H₃₈O₁₅

–H

1.8

637.21503, 445.15153, 323.07862, 251.05653

CD, CD-NP, CD-HP

72

Cis-Tubuloside B

C₃₁H₃₈O₁₆

–H

2.1

665.21032, 503.17680, 305.06585, 161.02529

CD, CD-NP, CD-HP

73

Crenatoside

C₂₉H₃₄O₁₅

–H

0.7

621.18264, 487.14611, 323.07878, 179.03579

CD, CD-NP, CD-HP

74

cistanoside C

C₃₀H₃₈O₁₅

–H

0.7

637.21389, 591.20868, 445.16991, 163.04078, 145.03032

CD, CD-NP, CD-HP

75

Osmanthuside B

C₂₉H₃₆O₁₃

–H

0.2

591.20804, 445.16991, 160.84291, 145.03032

CD, CD-NP, CD-HP

76

Eutigoside A

C₂₃H₂₆O₉

–H

0.2

445.15008, 163.03943, 145.03004

CD, CD-NP, CD-HP

77

Cistanoside M

C₃₀H₃₈O₁₄

 + HCOO

0.7

667.22446, 621.21761, 555.20753, 161.02534

CD, CD-NP, CD-HP

78

Isomartynoside

C₃₁H₄₀O₁₅

 + HCOO

1.2

697.23563, 651.22859, 475.17960, 175.04062

CD, CD-NP, CD-HP

79

Salsaside B

C₂₈H₃₄O₁₃

–H

0.8

503.17758, 323.07755, 161.02527

CD, CD-NP, CD-HP

80

2´-acetylacteoside

C₃₁H₃₈O₁₆

–H

2.6

665.21076, 503.17758, 305.06712, 161.02527

CD, CD-NP, CD-HP

81

Osmanthuside B

C₂₉H₃₆O₁₃

–H

0.6

445.1579, 163.0400, 145.0301

CD, CD-NP, CD-HP

82

Plantainoside C

C₃₀H₃₈O₁₅

–H

0.9

591.20986, 445.15921, 145.03022

CD, CD-NP, CD-HP

83

Kankanosides J1/J2

C₃₂H₄₀O₁₇

–H

0.3

695.21902, 649.21477, 503.17505, 145.03017

CD, CD-NP, CD-HP

84

SalsasideF

C₃₁H₃₈O₁₅

–H

0.8

649.21399, 503.17505, 347.16994, 145.03017

CD, CD-NP, CD-HP

85

Cistansinenside A

C₃₂H₄₀O₁₆

–H

0.8

679.22464, 623.19749, 161.02503

CD, CD-NP, CD-HP

86

isomartynoside

C₃₁H₄₀O₁₅

 + HCOO

1.6

697.23604, 651.22862, 505.16921, 175.04095

CD, CD-NP, CD-HP

87

Salsaside A

C₂₈H₃₄O₁₃

–H

1.1

577.19316, 501.16521, 469.13425, 179.03540, 161.02496

CD, CD-NP, CD-HP

88

Salsaside Ca/Cb

C₂₈H₃₄O₁₂

–H

0.6

561.19776, 415.16021, 163.04118, 145.03011

CD, CD-NP, CD-HP

89

SalsasideF

C₃₁H₃₈O₁₅

–H

1.2

649.21443, 503.17434, 461.16538

CD, CD-NP, CD-HP

90

Kankanosides J1/J2

C₃₂H₄₀O₁₇

–H

0.8

695.21948, 649.21421, 607.20459, 503.17401, 149.02394

CD, CD-NP, CD-HP

91

Osmanthuside B

C₂₉H₃₆O₁₃

–H

0.7

591.20845, 429.17830, 161.02556

CD, CD-NP, CD-HP

92

Jionoside D

C₃₀H₃₈O₁₅

–H

− 0.1

591.20842, 161.02556

CD, CD-NP, CD-HP

93

Salsaside D

C₃₁H₃₈O₁₅

–H

0.8

649.21401, 607.19810, 329.16152

CD, CD-NP, CD-HP

94

cistansinenside A

C₃₂H₄₀O₁₆

–H

1.3

679.22512, 637.21464, 461.16791, 161.02601

CD, CD-NP, CD-HP

95

Osmanthuside B6(Z)

C₂₉H₃₆O₁₃

–H

0.7

591.20854, 489.26955, 445.15395, 161.02652

CD, CD-NP, CD-HP

96

sinenside A

C₃₂H₄₀O₁₆

–H

1.7

679.22547, 633.22252, 591.20916, 145.03024

CD, CD-NP

97

Cistanoside M

C₃₀H₃₈O₁₄

–H

0.1

591.20868, 489.27111, 161.02535

CD, CD-NP