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Table 5 Stability and recovery of seven analytes

From: Chemical fingerprinting and quantitative constituent analysis of Siwu decoction categorized formulae by UPLC-QTOF/MS/MS and HPLC-DAD

Analytes

Stability (RSD,%; n = 6)

Recovery (%; n = 6)

A

B

C

D

E

SWD

THSWD

XFSWD

SFZYD

QLSWD

Mean

RSD (%)

Mean

RSD (%)

Mean

RSD (%)

Mean

RSD (%)

Mean

RSD (%)

Gallic acid

6.36

3.34

7.13

5.16

1.03

98.1

2.71

98.9

1.32

97.8

2.32

101.2

3.12

99.7

1.44

Protocatechuic acid

5.79

5.46

6.18

4.0

4.62

101.2

3.32

99.8

1.43

97.6

1.18

103.7

3.54

102.7

1.98

Vanillic acid

3.14

3.68

6.25

8.80

2.19

96.2

1.39

97.3

1.79

102.3

1.25

92.2

2.81

103.1

2.32

Caffeic acid

6.61

5.10

8.50

2.47

7.87

103.8

1.48

95.8

3.24

98.3

2.50

98.6

2.44

98.2

3.16

Paeoniflorin

6.13

3.79

7.37

8.36

4.07

97.1

3.25

98.2

2.77

95.4

1.15

94.0

1.36

95.8

2.17

Ferulic acid

4.54

3.74

1.31

7.65

2.10

99.7

1.22

103.2

1.94

99.3

1.43

97.5

2.65

104.6

1.89

Senkyunolide I

6.87

2.82

2.47

8.91

4.07

96.9

2.31

98.1

2.13

98.1

2.86

94.0

1.91

98.1

2.34