Structure | Position | δC | Position | δH, m, (J in Hz) |
---|---|---|---|---|
Stylopinea | 1 | 120.8 | 24 | 5.93, d (J = 10.62 Hz) |
1′ | 133.2 | 25 | 5.92, d (J = 10.61 Hz) | |
2 | 53.7 | 26 | 6.54, d (J = 0.44 Hz) | |
3 | – | 27 | 6.29, d (J = 0.43 Hz) | |
4 | 58.9 | 28 | 2.72, ddd (J = 13.46, 10.18, 3.41 Hz) | |
5 | 36.1 | 29 | 2.83, ddd (J = 13.46, 3.41, 2.23 Hz) | |
6 | 51.2 | 30 | 4.03, dd (J = 10.15, 3.49 Hz) | |
7 | 28.5 | 31 | 2.69, ddd (J = 13.96, 10.18, 3.14 Hz) | |
8 | 127.3 | 32 | 3.04, ddd (J = 13.96, 3.41, 2.23 Hz) | |
9 | 129.8 | 33 | 2.76, dd (J = 13.34, 3.49 Hz) | |
10 | 126.3 | 34 | 5.85, d (J = 10.51 Hz) | |
11 | 108.1 | 35 | 2.78, dd (J = 13.33, 10.15 Hz) | |
12 | 145.3 | 36 | 5.92, d (J = 10.52 Hz) | |
13 | 142.7 | 37 | 6.42, d (J = 8.62 Hz) | |
14 | 108.0 | 38 | 6.37, d (J = 8.61 Hz) | |
15 | 147.3 | 39 | 3.89, d (J = 11.90 Hz) | |
16 | 145.1 | 40 | 3.87, d (J = 11.91 Hz) | |
17 | 109.5 | Â | Â | |
18 | – |  |  | |
19 | 101.4 | Â | Â | |
20 | – |  |  | |
21 | – |  |  | |
22 | 101.2 | Â | Â | |
23 | – |  |  | |
Sanguinarinea | 1 | 106.3 | 25 | 33.32, d (J = 15.50 Hz) |
1′ | 148.7 | 26 | 33.33, d (J = 15.50 Hz) | |
2 | 132.9 | 27 | 7.65, t (J = 0.44 Hz) | |
3 | 128.2 | 28 | 7.64, dt (J = 1.55, 0.44 Hz) | |
4 | 106.3 | 29 | 8.10, dt (J = 6.19, 0.43 Hz) | |
5 | 148.0 | 30 | 8.12, ddd (J = 6.19, 1.55, 0.46 Hz) | |
6 | 126.7 | 31 | 4.19, s | |
7 | 126.5 | 32 | 4.18, s | |
8 | 128.5 | 33 | 4.19, s | |
9 | 138.4 | 34 | 9.71, d (J = 0.55 Hz) | |
10 | 130.0 | 35 | 6.51, d (J = 15.50 Hz) | |
11 | 116.7 | 36 | 6.50, d (J = 15.51 Hz) | |
12 | 144.2 | 37 | 7.03, d (J = 8.81 Hz) | |
13 | – | 38 | 8.53, ddd (J = 8.83, 0.55, 0.44 Hz) | |
14 | 126.1 | Â | Â | |
15 | 114.8 | Â | Â | |
16 | 147.4 | Â | Â | |
17 | 142.5 | Â | Â | |
18 | – |  |  | |
19 | 101.1 | Â | Â | |
20 | – |  |  | |
21 | – |  |  | |
22 | 101.3 | Â | Â | |
23 | – |  |  | |
24 | 46.1 | Â | Â |