No. | Compounds | Rt (min) | Fomula | Error (× 10–6) | Measured [M + H] +  | Major fragments | Calculated m/z | Structural type | KIS | KHS | KLS | KJS |
---|---|---|---|---|---|---|---|---|---|---|---|---|
(Measured [M + Na] +)[Measured  [2 M + Na]+] | ||||||||||||
1* | Vanillic Acid | 0.96 | C8H8O4 | − 4.17 | 169.0494 | 151.0385, 141,9584 | 168.0423 | phenolic acids | Y↓ | Y↑ | Y | Y |
2* | 7-O-Methylcedrusin | 1.35 | C20H24O6 | − 2.50 | 361.1642 | 331.1591, 151.0762 | 360.1573 | phenolics | Y | Y | Y | Y |
3* | ( +)-Pinoresinol | 1.98 | C20H22O6 | 4.18 | 359.1509 | 342.1393, 323.1288, 313.1444 | 358.1416 | lignans | Y↓ | Y | Y↑ | Y |
4* | Kadsutherin H | 3.7 | C24H26O9 | 0 | 459.1655 | 399.1460, 371.1475, 339.1221 | 458.1577 | lignans | Y | / | / | / |
5 | Micrandilactone I | 4.53 | C30H44O7 | 0.17 | 517.3161 | Â | 516.3087 | triterpenoids | / | / | Y | / |
6 | Kadsuranin | 4.87 | C23H28O6 | − 1.12 | 401.1954 |  | 400.1886 | lignans | Y↓ | Y | Y↑ | Y |
7* | Coumarinlignan | 4.89 | C20H16O7 | − 1.90 | 369.0967 | 351.0896, 321.0761, 203.0324 | 368.0896 | lignans | Y | Y | / | / |
8 | Schisantherin G | 4.99 | C29H34O11 | 2.34 | 559.2187 | Â | 588.2101 | lignans | / | / | Y | Y |
9 | Kadoblongifolin B | 5.43 | C22H24O8 | 1.92 | 417.1557 | 399.1437, 382.3145 | 416.1471 | lignans | Y | Y | Y↑ | Y↓ |
10* | Heteroclitin G | 5.57 | C22H24O7 | − 0.75 | 401.1597 | 383.1509, 341.1031, 313.1082 | 400.1522 | lignans | Y↑ | Y | Y | Y↓ |
11* | Kadsutherin F | 5.96 | C28H28O8 | 4.47 | 493.1884 | 403.1661, 401.1638,383.1509 | 492.1784 | lignans | Y | / | / | / |
12* | Schisandrol A | 6.22 | C24H32O7 | 3.93 | (455.2063) | 415.2180, 384.1929 | 432.2148 | lignans | Y | Y | Y | Y |
13 | Angeloylgomisin M1 | 6.28 | C27H32O8 | 4.13 | 485.2195 | 401.1617, 385.1644, 371.1505 | 484.2097 | lignans | Y↑ | Y↓ | Y | Y |
14* | Interiorin C | 6.35 | C24H26O8 | 4.98 | 443.1728 | 383.1509, 355.1547 | 442.1628 | lignans | Y↑ | Y | Y | Y |
15* | Heteroclitin E | 6.49 | C27H30O9 | 0.80 | 499.1972 | 399.1450, 371.1515, 339.1221 | 498.189 | lignans | Y | Y | Y | / |
16* | Benzoyl Oxokadsuranol | 6.64 | C29H28O9 | − 1.92 | 521.1801 | 503.1685, 399.1460, 371.1475 | 520.1733 | lignans | Y | Y | Y | Y |
17* | Schisantherin E | 6.96 | C30H34O9 | − 4.27 | (561.2078) | 417.1923, 373.1645 | 538.2203 | lignans | / | / | Y | / |
18 | Longipedlignan H | 6.97 | C24H26O9 | − 1.53 | 459.1648 | 399.1460, 355.1161, 327.1205 | 458.1577 | lignans | Y | Y↑ | Y↓ | Y |
19 | Longipedlignan E | 7.03 | C27H32O9 | 2.26 | [1023.4008] | Â | 500.2046 | lignans | / | Y | / | / |
20 | 4β,9β-dihydroxy-1α,5α-H-guaia-6,10 (14)-dien | 7.07 | C15H24O2 | 1.69 | 236.178 | 219.1757, 194.1159 | 236.1776 | sesquiterpenoids | Y | Y↑ | Y | Y↓ |
21 | Acetoxyl Oxokadsurane | 7.63 | C24H26O8 | 2.26 | 443.1688 | 383.1468, 355.1547 | 442.16 | lignans | / | / | Y | / |
22 | Longipedlactone C | 7.66 | C30H40O6 | 3.31 | 497.2914 | Â | 496.2825 | triterpenoids | / | Y | Y | Y |
23 | Piperitol | 7.8 | C20H20O6 | 0 | 357.1338 | 311.0954, 222.1118 | 356.126 | lignans | Y | Y↓ | Y↑ | Y |
24 | Kadoblongifolin A, Kadoblongifolin B | 8.65 | C22H24O8 | − 0.48 | 417.1547 | 385.1685, 354.2850, 315.0891 | 416.1471 | lignans | Y | Y | Y↓ | Y↑ |
25 | Schizanrin M | 8.75 | C22H24O7 | 0.50 | 401.1602 | 383.1576, 354.2850, 186.0572 | 400.1522 | lignans | Y | Y | Y↑ | Y↓ |
26 | 6-hydroxyhinokinin | 8.85 | C20H18O7 | 3.24 | (393.0963) | 357.1370, 325.1088 | 370.1053 | lignans | Y↓ | Y↑ | Y | Y |
27 | Interiotherin B | 9.01 | C27H30O9 | 0.80 | 499.1972 | 399.1437, 382.3145, 355.1175, 325.1088, 279.0919 | 498.189 | lignans | Y↑ | Y↓ | Y | Y |
28 | Angeloylbinankadsurin A | 9.21 | C27H32O8 | − 0.41 | 485.2186 | 385.1644, 354.2850 | 484.211 | lignans | Y↓ | Y | Y | Y↑ |
29 | Gomisin J | 9.67 | C22H28O6 | − 2.65 | 389.1948 |  | 388.1886 | lignans | Y | Y | / | Y |
30 | Kadsulignan I | 10.34 | C25H28O8 | 1.32 | 457.1868 | 371.1492, 356.1256 | 456.1784 | lignans | Y↑ | Y↓ | Y | Y |
31 | Angeloylgomisin R | 10.49 | C27H30O8 | 0 | 483.2019 | 383.1492, 368.1260 | 482.1941 | lignans | Y↑ | Y | Y↓ | Y |
32 | Interiorin D | 10.92 | C29H28O8 | − 0.99 | 505.1861 | 497.1571 | 504.1788 | lignans | Y↑ | Y | Y↓ | Y |
33 | Heteroclitin O | 11.22 | C34H32O11 | 2.84 | 617.2035 | Â | 616.1945 | lignans | / | / | Y | / |
34 | Longipedlignan I | 11.48 | C26H30O9 | 2.41 | 486.1902n | Â | 486.189 | lignans | Y | Y | Y | Y |
35 | Schizanrin F | 11.51 | C32H34O11 | 1.19 | 595.2181 |  | 594.2101 | lignans | Y↓ | Y | Y↑ | Y |
36 | Kadnanolactone A | 11.65 | C30H38O5 | 1.25 | 479.2803 | 432.2034, 415.1756 | 478.2719 | triterpenoids | Y↓ | Y↑ | Y | Y |
37 | ( +)-Gomisin K3 | 12.04 | C23H30O6 | 0.62 | 403.2118 |  | 402.2042 | lignans | Y | Y | Y | Y |
38 | Heteroclitin C, Heteroclitin B | 12.11 | C28H34O8 | 3.38 | (521.2163) |  | 498.2254 | lignans | Y | Y↓ | Y↑ | Y |
39 | Kadlongilignan E | 12.34 | C27H30O9 | − 0.20 | 499.1967 | 483.2374, 399.1437, 369.1348 | 498.189 | lignans | / | Y↓ | Y↑ | / |
40* | Heteroclitin D | 12.65 | C27H30O8 | − 4.77 | 483.1996 | 383.1549, 366.1547, 323.1251 | 482.1941 | lignans | Y↑ | Y | Y | Y↓ |
41 | Longipedlactone B | 13.2 | C30H40O5 | 1.62 | 481.2956 |  | 480.2876 | triterpenoids | / | Y | Y | Y↑ |
42 | Licarin A | 13.36 | C20H22O4 | − 4.91 | 327.158 | 270.3151, 229.1418, 182.9854 | 326.1518 | lignans | Y | Y | Y | Y |
43* | Schisantherin A | 13.43 | C30H32O9 | − 2.05 | (559.1933) | 415.1763, 371.1475, 340.1289 | 536.2046 | lignans | / | Y↑ | Y↓ | Y |
44* | Schisantherin B | 13.45 | C28H34O9 | 1.36 | (537.2108) | 415.1805, 371.1475 | 514.2203 | lignans | / | Y | Y | Y |
45* | Kadsurin | 15.53 | C25H30O8 | − 4.36 | 459.1999 | 400.1850, 369.1675, 354.1414 | 458.1941 | lignans | Y | / | / | / |
46 | Isoanwulignan, ( +)-anwulignan | 16.38 | C20H24O4 | 3.00 | (351.1577) |  | 328.1675 | lignans | Y | Y | Y | Y |
47 | Interiotherin C | 16.75 | C30H36O10 | 4.42 | (579.2225) | 457.1851, 357.1331 | 556.2308 | lignans | Y | Y | Y | / |
48 | Gomisin A (Schisandrol B), Gomisin O | 16.84 | C23H28O7 | 3.87 | 417.1924 |  | 416.1835 | lignans | Y↓ | Y↑ | Y | Y |
49 | Schiarisanrin D | 16.98 | C31H30O8 | 1.13 | 531.2025 | 383.1471, 355.1522, 186.0572 | 530.1941 | lignans | Y | Y | Y | / |
50* | D-Epigalbacin | 18.16 | C20H20O5 | − 4.70 | 341.1373 | 323.1269, 302.3088, 279.0953 | 340.1311 | lignans | / | / | Y | / |
51 | Schizandrin | 18.2 | C24H32O7 | 0 | (455.2031) | 385.1644, 354.2889, 279.0919 | 432.2148 | lignans | / | Y | / | / |
52* | Gomisin N | 20.07 | C23H28O6 | 0.50 | 401.1966 | 370.1750, 355.1541 | 400.1886 | lignans | Y↑ | Y | Y | Y |
53 | Schizandrin C | 21.25 | C22H24O6 | 3.64 | (407.1485) | 385.1641, 301.1434 | 384.1573 | lignans | / | / | Y | / |
54 | Heteroclitin A, Caproylbinankadsurin A | 22.02 | C28H36O8 | 4.23 | (523.2324) | Â | 500.241 | lignans | / | Y | / | / |
55* | Manwuwezic Acid | 26.21 | C30H46O4 | 4.46 | 471.3495 | 453.3355 | 470.3396 | triterpenoids | Y | Y | Y | Y |
56* | Prinsepiol | 29.77 | C20H22O8 | 2.05 | 391.1401 | 371.3170, 284.2935, 279.1594 | 390.1315 | lignans | Y | Y | Y | Y |