Table 1 1H (500 MHz) and 13C NMR (125 MHz) data of 1 and 7 (δ in ppm, CDCl3)
Position | 1 | 7 | ||
|---|---|---|---|---|
δH (mlti., J in Hz) | δC | δH (mlti., J in Hz) | δC | |
2 | 5.35, t (3.5) | 100.6 | 7.84, s | 152.3 |
3 | 2.99, dd (17.1, 3.7) 2.75, dd (17.1, 3.2) | 41.8 | Â | 123.8 |
4 | Â | 194.3 | Â | 181.2 |
5 | Â | 156.3 | Â | 165.3 |
6 | Â | 103.3 | 6.29, s | 95.1 |
7 | Â | 159.7 | Â | 163.4 |
8 | Â | 108.9 | Â | 113.0 |
9 | Â | 155.2 | Â | 153.4 |
10 | Â | 102.8 | Â | 106.3 |
1ʹ |  |  |  | 122.9 |
2ʹ |  |  | 7.33, d (7.9) | 130.5 |
3ʹ |  |  | 6.84, d (8.0) | 115.9 |
4ʹ | 6.61, d (10.0) | 115.6 |  | 156.3 |
5ʹ | 5.48, d (10.0) | 125.9 | 6.84, d (8.0) | 115.7 |
6ʹ |  | 78.1 | 7.33, d (7.9) | 130.5 |
1ʺ | 3.27, dd (14.0, 7.6) 3.20, dd (14.0, 6.8) | 21.4 |  | 43.9 |
2ʺ | 5.14, m | 122.7 | 4.52, q (6.6) | 91.0 |
3ʺ |  | 131.0 | 1.50, s | 25.8 |
4ʺ | 1.66, s | 25.7 | 1.25, s | 21.6 |
5ʺ | 1.78, s | 17.8 | 1.40, d (6.6) | 14.3 |
2-OCH3 | 3.47, s | 56.3 | Â | Â |
6ʹ-CH3 | 1.44, s 1.42, s | 28.4 28.3 |  |  |